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The functionality and performance of a semiconductor is determined by its bandgap. Alloying, as for instance in InxGa1-xN, has been a mainstream strategy for tuning the bandgap. Keeping the semiconductor alloys in the miscibility gap (being homogeneous), however, is non-trivial. This challenge is now being extended to halide perovskites – an emerging class of photovoltaic materials. While the bandgap can be conveniently tuned by mixing different halogen ions, as in CsPb(BrxI1-x)3, the so-called mixed-halide perovskites suffer from severe phase separation under illumination. Here, we discover that such phase separation can be highly suppressed by embedding nanocrystals of mixed-halide perovskites in an endotaxial matrix. The tuned bandgap remains remarkably stable under extremely intensive illumination. The agreement between the experiments and a nucleation model suggests that the size of the nanocrystals and the host-guest interfaces are critical for the photo-stability. The stabilized bandgap will be essential for the development of perovskite-based optoelectronics, such as tandem solar cells and full-color LEDs. 

Abstract Unaweep Canyon (Uncompahgre Plateau, Colorado) represents an enigmatic landscape with a complex evolution. Interpretations for its origin have ranged from ancestral fluvial erosion in the late Cenozoic to glacial erosion in the Paleozoic, or some combination thereof, with significant implications for global climatic and large‐scale tectonic reconstructions. To address the conflicting interpretations, we acquired a high‐resolution seismic reflection profile to investigate the depth, structure, and sedimentary infill in the canyon. The data set is further complemented with an electrical resistivity survey. Integrated with other geophysical and geological data, the results show an overdeepened Precambrian basement with transverse U shape and support the hypothesis of a pre‐Quaternary glacial origin. Our data constitute the first detailed image of a buried pre‐Quaternary glacial valley in North America; if substantiated with core studies, these results have far‐reaching implications for our understanding of global ice houses as well as the tectonic conditions, enabling preservation of such systems.